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Title: In-situ production of PH3 from red phosphorus and atomic hydrogen
Authors: Umemoto, Hironobu
Nishihara, Yushin
Ishikawa, Takuma
Journal Title: Chemical Physics Letters
Publisher: Elsevier
Journal Volume: 514
Journal Issue: 1-3
Start Page: 26
End Page: 28
Issue Date: 2011-08-12
Rights: © 2011 Elsevier B.V. All rights reserved.
NDC: 431
Abstract: The production of PH3 from red phosphorus and the atomic hydrogen formed in the catalytic decomposition of H2 on heated W surfaces was confirmed. The absolute density of the PH3 could be as high as 1013 cm−3; the density was proportional to H-atom density in the absence of red phosphorus, although three H atoms must be involved in the production of one PH3 molecule, but showed minor dependence on the amount of red phosphorus. These results suggest that the rate-determining step for the production of PH3 is that which produces H atoms.
ISSN: 00092614 OPAC
Publisher's DOI: 10.1016/j.cplett.2011.08.014   
Journal NCID: AA00602122 OPAC ciniib
Textversion: author
Appears in Collections:05. 雑誌論文・記事(Journal Article, Article, Preprint)

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Others By: Umemoto, Hironobu (梅本, 宏信) (ウメモト, ヒロノブ) -- Nishihara, Yushin -- Ishikawa, Takuma

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